Hello Muzzol!
ZeXtras Powerstore does not allow any operation on index volumes, and as far as I know neither does Zimbra Network Edition.
You could always mount a new disk on a path of your choice, stop zimbra, move all the data from the /opt/zimbra/index/ directory to the newly mounted path, unmount the new disk, mount it back on /opt/zimbra/index/ and start Zimbra...
Nothing should go wrong, but this is something I'd personally avoid to do (please take into account that I'm a bit paranoid when it comes to prod servers

).
Cine
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